Project NextGen publishes new review paper on borate-based compounds as cathode materials for advanced batteries

Dec 19, 2022
Project NextGen of LEE proudly presents the recently published review paper titled "𝗕𝗼𝗿𝗮𝘁𝗲-𝗕𝗮𝘀𝗲𝗱 𝗖𝗼𝗺𝗽𝗼𝘂𝗻𝗱𝘀 𝗮𝘀 𝗠𝗶𝘅𝗲𝗱 𝗣𝗼𝗹𝘆𝗮𝗻𝗶𝗼𝗻 𝗖𝗮𝘁𝗵𝗼𝗱𝗲 𝗠𝗮𝘁𝗲𝗿𝗶𝗮𝗹𝘀 𝗳𝗼𝗿 𝗔𝗱𝘃𝗮𝗻𝗰𝗲𝗱 𝗕𝗮𝘁𝘁𝗲𝗿𝗶𝗲𝘀" by Giancarlo Dominador D. Sanglay, Jayson S. Garcia, Mecaelah S. Palaganas, Maurice Sorolla, Sean See, Lawrence A. Limjuco, and Joey D. Ocon of the 𝐏𝐫𝐨𝐣𝐞𝐜𝐭 𝐍𝐞𝐱𝐭𝐆𝐞𝐧, 𝗔𝗱𝘃𝗮𝗻𝗰𝗲𝗱 𝗕𝗮𝘁𝘁𝗲𝗿𝗶𝗲𝘀 𝗖𝗲𝗻𝘁𝗲𝗿 𝗣𝗵𝗶𝗹𝗶𝗽𝗽𝗶𝗻𝗲𝘀.

Borate-based compounds offer tunability and versatility as potential cathode materials due to their (1) diverse structures that can host alkali metal intercalation; (2) low weight of borate relative to mature polyanion families, which can translate to higher theoretical capacity; and (3) rich chemistry that can alter the inductive effect on earth-abundant transition metals. Furthermore, its natural abundance and hence, cost advantage can contribute to its capacity as a cost-effective, high-performance cathode material for secondary batteries.

The untapped potential of borate-based compounds inspired the authors to provide a thorough review of the structures, properties, and synthesis routes of identified borate-based compounds (i.e., borophosphate (BPO), borosulfate (BSO), and borosilicate (BSiO)), as well as their potential application as mixed polyanion cathode materials for next-generation batteries. 

This article is part of the Special Issue "𝐒𝐲𝐧𝐭𝐡𝐞𝐬𝐢𝐬 𝐚𝐧𝐝 𝐂𝐡𝐚𝐫𝐚𝐜𝐭𝐞𝐫𝐢𝐳𝐚𝐭𝐢𝐨𝐧 𝐨𝐟 𝐅𝐮𝐧𝐜𝐭𝐢𝐨𝐧𝐚𝐥 𝐌𝐚𝐭𝐞𝐫𝐢𝐚𝐥𝐬 𝐟𝐨𝐫 𝐄𝐥𝐞𝐜𝐭𝐫𝐨𝐜𝐡𝐞𝐦𝐢𝐜𝐚𝐥 𝐄𝐧𝐞𝐫𝐠𝐲 𝐒𝐭𝐨𝐫𝐚𝐠𝐞 𝐚𝐧𝐝 𝐂𝐨𝐧𝐯𝐞𝐫𝐬𝐢𝐨𝐧" of Molecules MDPI.
You may access and read the full paper through this link: https://www.mdpi.com/1420-3049/27/22/8047 
𝗞𝗲𝘆𝘄𝗼𝗿𝗱𝘀: cathode; battery; mixed polyanion; borophosphate; borosulfate; borosilicate
𝘛𝘩𝘪𝘴 𝘸𝘰𝘳𝘬 𝘪𝘴 𝘧𝘶𝘯𝘥𝘦𝘥 𝘣𝘺 𝘵𝘩𝘦 𝘋𝘦𝘱𝘢𝘳𝘵𝘮𝘦𝘯𝘵 𝘰𝘧 𝘚𝘤𝘪𝘦𝘯𝘤𝘦 𝘢𝘯𝘥 𝘛𝘦𝘤𝘩𝘯𝘰𝘭𝘰𝘨𝘺 (𝘋𝘖𝘚𝘛) 𝘵𝘩𝘳𝘰𝘶𝘨𝘩 𝘵𝘩𝘦 𝘕𝘪𝘤𝘩𝘦 𝘊𝘦𝘯𝘵𝘦𝘳𝘴 𝘪𝘯 𝘵𝘩𝘦 𝘙𝘦𝘨𝘪𝘰𝘯𝘴 𝘧𝘰𝘳 𝘙&𝘋 (𝘕𝘐𝘊𝘌𝘙) 𝘗𝘳𝘰𝘨𝘳𝘢𝘮.
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𝗔𝗱𝘃𝗮𝗻𝗰𝗲𝗱 𝗕𝗮𝘁𝘁𝗲𝗿𝗶𝗲𝘀 𝗖𝗲𝗻𝘁𝗲𝗿 𝗣𝗵𝗶𝗹𝗶𝗽𝗽𝗶𝗻𝗲𝘀 (𝗔𝗕𝗖 𝗣𝗛) is a collaborative R&D program between Technological Institute of the Philippines (TIP) and University of the Philippines Diliman (UPD) funded by the Department of Science and Technology (DOST) through DOST-Science for Change Program. The three projects under this program focus on innovating different battery chemistries.
The 𝗡𝗲𝘅𝘁𝗚𝗲𝗻 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 aims to develop advanced cathode materials for next-generation batteries. The 𝗥𝗘𝗕𝗖𝗲𝗹𝗹 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 targets to renew the Edison Battery using advanced cell architecture. 𝗔𝗟𝗔𝗕-𝗘𝗨 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 pursues to develop advanced lead acid batteries with embedded ultrasonics.
By Mecaelah Palaganas 12 Apr, 2024
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By Mecaelah Palaganas 12 Apr, 2024
The National Academy of Science and Technology Philippines (NAST PHL) conducted a three-part webinar series on the Innovations for Human and Planet Health and Security to promote open innovation and collaboration as a defining factor of socio-economic development. Highly esteemed NAST members of the representative divisions of various fields in science, awardees, and experts were invited to tackle the current innovation ecosystem of the Philippines and the innovative solutions that address food security and climate change. Aimed to promote multidisciplinary discourse and partnerships, the event was participated by researchers, policymakers, government officials, and the general public. Among the prestigious roster of resource speakers was Prof. Joey D. Ocon who delivered his talk on “Next Generation Batteries and Green Hydrogen with Renewables: Opportunities in the Clean Energy Transition” during the third segment of the NAST PHL Innovation Series. Prof. Ocon shared insights on the crucial role of energy storage technologies in the transition to renewable energy sources and the scalability of energy systems that can help satisfy the energy demand in the country. As part of the vertically-integrated R&D agenda of the Laboratory of Electrochemical Engineering (LEE), he also introduced water electrolyzer technologies involved in the production of Green Hydrogen. Moreover, the research facilities in LEE such as the CHED-LAKAS funded Hydrogen as Vector for Energy (HyVE) Research Facility and the DOST-NICER funded Advanced Batteries Center, both of which are first of its kind within the country, were highlighted as well as their capabilities and future endeavors. In the area of commercialization, Prof. Ocon discussed the multi-scale approach of the startup Nascent Technologies Corporation and its mission on industrial decarbonization by providing technologies and solutions for various energy storage applications. Through information dissemination in his thematic talk, more innovators and collaborators can come forward in support of the vision of the ongoing projects led by Prof. Ocon and devise integrative innovations that can contribute to the clean energy transition in the Philippines. Reference: https://nast.dost.gov.ph/index.php/13-news-press-releases/752-nast-phl-to-conduct-webinar-series-on-innovations-for-food-security-climate-change
By Mecaelah Palaganas 20 Mar, 2024
Researchers of 𝗔𝗕𝗖 𝗣𝗛’𝘀 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 𝗡𝗲𝘅𝘁𝗚𝗲𝗻 has achieved a significant breakthrough: the development of the 𝐏𝐡𝐢𝐥𝐢𝐩𝐩𝐢𝐧𝐞𝐬' 𝐟𝐢𝐫𝐬𝐭 𝐒𝐨𝐝𝐢𝐮𝐦-𝐈𝐨𝐧 𝐁𝐚𝐭𝐭𝐞𝐫𝐢𝐞𝐬 (𝐒𝐈𝐁𝐬). These batteries incorporated three families of cathodes such as 𝙋𝙧𝙪𝙨𝙨𝙞𝙖𝙣 𝘽𝙡𝙪𝙚 𝘼𝙣𝙖𝙡𝙤𝙜𝙪𝙚𝙨 (𝙋𝘽𝘼𝙨), 𝙇𝙖𝙮𝙚𝙧𝙚𝙙 𝙏𝙧𝙖𝙣𝙨𝙞𝙩𝙞𝙤𝙣 𝙈𝙚𝙩𝙖𝙡 𝙊𝙭𝙞𝙙𝙚𝙨 (𝙇𝙏𝙈𝙊𝙨), 𝙖𝙣𝙙 𝙋𝙤𝙡𝙮𝙖𝙣𝙞𝙤𝙣𝙞𝙘 𝘾𝙤𝙢𝙥𝙤𝙪𝙣𝙙𝙨. With abundant and cost-effective sodium, SIBs offer a sustainable alternative to traditional lithium-ion batteries, holding immense potential for renewable energy applications. This achievement showcases 𝗙𝗶𝗹𝗶𝗽𝗶𝗻𝗼 𝗶𝗻𝗻𝗼𝘃𝗮𝘁𝗶𝗼𝗻 and sets the stage for a cleaner, more sustainable energy landscape. --- 𝗔𝗱𝘃𝗮𝗻𝗰𝗲𝗱 𝗕𝗮𝘁𝘁𝗲𝗿𝗶𝗲𝘀 𝗖𝗲𝗻𝘁𝗲𝗿 𝗣𝗵𝗶𝗹𝗶𝗽𝗽𝗶𝗻𝗲𝘀 (𝗔𝗕𝗖 𝗣𝗛) is a collaborative R&D program between Technological Institute of the Philippines (TIP) and University of the Philippines Diliman (UPD) funded by the Department of Science and Technology (DOST) through DOST-Science for Change Program. The three projects under this program focus on innovating different battery chemistries. The 𝗡𝗲𝘅𝘁𝗚𝗲𝗻 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 aims to develop advanced cathode materials for next-generation batteries. The 𝗥𝗘𝗕𝗖𝗲𝗹𝗹 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 targets to renew the Edison Battery using advanced cell architecture. 𝗔𝗟𝗔𝗕-𝗘𝗨 𝗣𝗿𝗼𝗷𝗲𝗰𝘁 pursues to develop advanced lead acid batteries with embedded ultrasonics.
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